| Jornada 1 | 18/08/2013 | FC BARCELONA | 7 | LEVANTE | 0 |
| Jornada 2 | 25/08/2013 | MALAGA | 0 | FC BARCELONA | 1 |
| Jornada 3 | 01/09/2013 | VALENCIA | 2 | FC BARCELONA | 3 |
| Jornada 4 | 15/09/2013 | FC BARCELONA | 3 | SEVILLA | 2 |
| Jornada 5 | 22/09/2013 | RAYO VALLEC. | 0 | FC BARCELONA | 4 |
| Jornada 6 | 25/09/2013 | FC BARCELONA | 4 | REAL SOCIEDAD | 1 |
| Jornada 7 | 29/09/2013 | ALMERIA | 0 | FC BARCELONA | 2 |
| Jornada 8 | 06/10/2013 | FC BARCELONA | 4 | VALLADOLID | 1 |
| Jornada 9 | 20/10/2013 | OSASUNA | 0 | FC BARCELONA | 0 |
| Jornada 10 | 27/10/2013 | FC BARCELONA | 2 | REAL MADRID | 1 |
| Jornada 11 | 30/10/2013 | CELTA | 0 | FC BARCELONA | 3 |
| Jornada 12 | 03/11/2013 | FC BARCELONA | 1 | ESPANYOL | 0 |
| Jornada 13 | 10/11/2013 | BETIS | 1 | FC BARCELONA | 4 |
| Jornada 14 | 24/11/2013 | FC BARCELONA | 4 | GRANADA | 0 |
| Jornada 15 | 01/12/2013 | ATHLETIC BILBAO | 1 | FC BARCELONA | 0 |
| Jornada 16 | 15/12/2013 | FC BARCELONA | 2 | VILLARREAL | 1 |
| Jornada 17 | 22/12/2013 | GETAFE | 2 | FC BARCELONA | 5 |
| Jornada 18 | 05/01/2014 | FC BARCELONA | 4 | ELCHE | 0 |
| Jornada 19 | 12/01/2014 | ATLETICO MADRID | 0 | FC BARCELONA | 0 |
| Jornada 20 | 19/01/2014 | LEVANTE | 1 | FC BARCELONA | 1 |
| Jornada 21 | 26/01/2014 | FC BARCELONA | 3 | MALAGA | 0 |
| Jornada 22 | 02/02/2014 | FC BARCELONA | 2 | VALENCIA | 3 |
| Jornada 23 | 09/02/2014 | SEVILLA | 1 | FC BARCELONA | 4 |
| Jornada 24 | 16/02/2014 | FC BARCELONA | 6 | RAYO VALLEC. | 0 |
| Jornada 25 | 23/02/2014 | REAL SOCIEDAD | 3 | FC BARCELONA | 1 |
| Jornada 26 | 02/03/2014 | FC BARCELONA | 4 | ALMERIA | 1 |
| Jornada 27 | 09/03/2014 | VALLADOLID | 1 | FC BARCELONA | 0 |
| Jornada 28 | 16/03/2014 | FC BARCELONA | 7 | OSASUNA | 0 |
| Jornada 29 | 23/03/2014 | REAL MADRID | 3 | FC BARCELONA | 4 |
| Jornada 30 | 26/03/2014 | FC BARCELONA | 3 | CELTA | 0 |
| Jornada 31 | 30/03/2014 | ESPANYOL | 0 | FC BARCELONA | 1 |
| Jornada 32 | 06/04/2014 | FC BARCELONA | 3 | BETIS | 1 |
| Jornada 33 | 13/04/2014 | GRANADA | 1 | FC BARCELONA | 0 |
| Jornada 34 | 20/04/2014 | FC BARCELONA | 2 | ATHLETIC BILBAO | 1 |
| Jornada 35 | 27/04/2014 | VILLARREAL | 2 | FC BARCELONA | 3 |
| Jornada 36 | 04/05/2014 | FC BARCELONA | 2 | GETAFE | 2 |
| Jornada 37 | 11/05/2014 | ELCHE | 0 | FC BARCELONA | 0 |
| Jornada 38 | 18/05/2014 | FC BARCELONA | 1 | ATLETICO MADRID | 1 |